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VISUAL CHEMISTRY

GROUP I : THE ALKALI METALS : PRECIPITATE REACTIONS

Alkali metal hydroxides can be used to test the identity of metals in certain salts.
 

sodium hydroxide + metal salt sodium salt + metal hydroxide ↓

The colour of the precipitate will help identify the metal:

  • Calcium hydroxide is soluble; no precipitate is formed

  • Copper hydroxide forms a blue precipitate

  • Iron II hydroxide forms a green precipitate

  • Iron III hydroxide forms a red-brown precipitate

  • Zinc hydroxide forms a jelly-like, white precipitate

  • Aluminium hydroxide forms a white precipitate that will re-dissolve as the reaction proceeds.

1. Sodium hydroxide with calcium sulphate

No precipitate is formed since calcium hydroxide is soluble in water.

CaSO4 + 2NaOH  Na2SO4 + Ca(OH)2

2. Sodium hydroxide with iron III chloride

A red-brown precipitate is formed.

FeCl3+ 3NaOH   3NaCl  Fe(OH)3

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