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VISUAL CHEMISTRY

GROUP I : THE ALKALI METALS : REACTIONS

.1. With oxygen gas

A small amount of the metal oxide is produced but the majority of the product is the metal peroxide.

The metal will burn with a characteristic colour. Sodium gives a yellow flame, lithium a red flame and potassium a lilac-coloured flame.
 

Formation of the oxide: 4Na + O2  2Na2O
 

Formation of the metal peroxide: 2Na + O2  Na2O2
 


2. With hydrogen gas

The metal is heated as hydrogen gas is passed over it. The metal hydride is formed.

2Na + H2  2NaH

3. With water

Lithium reacts less quickly than the other alkali metals. The reaction can be quite explosive with the more reactive metals. A piece of potassium will move quickly over he surface of the water and a small, lilac flame is sometimes seen. The metal hydroxide is formed and hydrogen is released.

2Na + 2H2 2NaOH  + H2­

4. With halogens

The corresponding salt is formed. The example shows sodium reacting with chlorine gas.

2Na + Cl2  2NaCl

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